Journal of Environmental Accounting and Management
Synergistic Approaches for Environmental Risk Mitigation in Copper Industry: Bottom-up Emission Modeling and Whole-Process Reduction
Journal of Environmental Accounting and Management 13(1) (2025) 77--90 | DOI:10.5890/JEAM.2025.03.007
Na Li$^{1}$, Huan You$^{1}$, Chengkang Gao$^{1}$, Zhenjiang Guo$^{2}$, Yanzheng Wu$^{1}$, Xinhong Zhang$^{1}$
$^1$ School of Metallurgy, Northeastern University, Shenyang, Liaoning 110819, China
$^2$ Liaoning Province Huludao Ecological environment Monitoring Center, Liaoning Province, Huludao 125000, China
Download Full Text PDF
Abstract
The rapid growth of China's economy and industrialization has heightened pollutant emissions and environmental risks in the copper industry. Despite implementing emission standards to reduce pollution from the copper industry, issues remain. For instance, there is a lack of quantitative trajectory studies and systematic approaches to emission reduction. Therefore, this study adopted a bottom-up emission model to develop pollutant emission inventories for China's copper smelting industry in 2010, 2015, and 2020, followed by an analysis of their spatiotemporal characteristics. Additionally, a genetic algorithm-optimized neural network model and scenario analysis method were employed to quantify the pollutant reduction potential and environmental governance effects of comprehensive emission reduction measures. The results indicate that in 2020, the total emissions of key pollutants (SO${}_{2}$, As, Pb, and Cd) in the copper smelting industry were 183.67kt, 70.76t, 37.7t, and 17.15t, respectively. Smelting and converting processes were identified as the main pollution sources, accounting for over 95\% of the total emissions. Temporally, emissions of heavy metals As, Pb, and Cd showed a continuous increasing trend, while the growth rate of SO${}_{2}$ emissions slowed. Spatially, pollutant emissions presented an uneven distribution influenced by economic development and mineral resources. For instance, Jiangxi (18.38t), Jiangsu (9.48t), Guangdong (9.06t), Zhejiang (8.61t), and Anhui (6.64t) were the provinces with the highest emissions of heavy metal As. Scenario analysis indicates that by 2030, emissions of As are expected to decrease by 17.73t, 10.23t, and 24.87t under source reduction, process control, and end-of-pipe treatment measures, respectively.
Acknowledgments
The funding for this research was provided by the Based Research Projects of the National Natural Science Foundation of China (41871212), the Second Tibetan Plateau Scientific Expedition and Research Program (2019QZKK1003), and the Fundamental Research Funds for the Central Universities (N2025008).
References
-
[1]  | National Bureau of Statistics, (2021), China Statistical Yearbook.
|
-
[2]  | Guo, X., Chen, Y., Wang, Q., Wang, S., and Tian, Q. (2022), Copper and arsenic substance flow analysis of pyrometallurgical process for copper production, Transactions of Nonferrous Metals Society of China, 32, 364-376.
|
-
[3]  | Li, X., Wang, X., Cai, B., Wang, L., Yuan, L., and Ning, P. (2023), Investigation of heavy metal flows in a copper pyrometallurgical process of a typical smelter, Process Safety and Environmental Protection, 174, 214-222.
|
-
[4]  | Mi, Y., Zhou, Jun, Liu, M., Liang, J., Kou, L., Xia, R., Tian, R., and Zhou, J. (2023), Machine learning method for predicting cadmium concentrations in rice near an active copper smelter based on chemical mass balance, Chemosphere, 319, 138028.
|
-
[5]  | Yang, J., Guo, Z., Jiang, L., Sarkodie, E.K., Li, K., Shi, J., Deng, Y., Zhang, Z., Liu, H., Liang, Y., Yin, H., and Liu, X. (2022), Cadmium, lead and arsenic contamination in an abandoned nonferrous metal smelting site in southern China: Chemical speciation and mobility, Ecotoxicology and Environmental Safety, 239, 113617.
|
-
[6]  | Yao, L., Min, X., Xu, H., Ke, Y., Wang, Y., Lin, Z., Liang, Y., Liu, D., Xu, Q., and He, Y. (2020), Physicochemical and environmental properties of arsenic sulfide sludge from copper and lead-zinc smelter, Transactions of Nonferrous Metals Society of China, 30, 1943-1955.
|
-
[7]  | Zhang, Y., Tang, X., Yi, H., and Ma, J. (2013), Estimation of SO${}_{2}$ emission factors from copper smelting industry in Yunnan Province, China Journal of Central South University, 20, 742-748.
|
-
[8]  | Shao, X., Cheng, H., Li, Q., and Lin, C. (2013), Anthropogenic atmospheric emissions of cadmium in China, Atmospheric Environment, 79, 155-160.
|
-
[9]  | Ye, X., Hu, D., Wang, H., Chen, L., Xie, H., Zhang, W., Deng, C., and Wang, X. (2015), Atmospheric mercury emissions from China's primary nonferrous metal (Zn, Pb and Cu) smelting during 1949-2010, Atmospheric Environment, 103, 331-338.
|
-
[10]  | Tian, H.Z., Zhou, J., Zhu, C., Zhao, D., Gao, J., Hao, J., He, M., Liu, K., Wang, K., and Hua, S. (2014), A Comprehensive Global Inventory of Atmospheric Antimony Emissions from Anthropogenic Activities, 1995-2010, Environmental Science \& Technology, 48, 10235-10241.
|
-
[11]  | Pacyna, E.G., Pacyna, J.M., Sundseth, K., Munthe, J., Kindbom, K., Wilson, S., and Maxson, P. (2010), Global emission of mercury to the atmosphere from anthropogenic sources in 2005 and projections to 2020, Atmospheric Environment, 44, 2487-2499.
|
-
[12]  | Tian, H.Z., Zhu, C.Y., Gao, J.J., Cheng, K., Hao, J.M., Wang, K., Hua, S.B., Wang, Y., and Zhou, J.R. (2015), Quantitative assessment of atmospheric emissions of toxic heavy metals from anthropogenic sources in China: historical trend, spatial distribution, uncertainties, and control policies, Atmospheric Chemistry and Physics, 15, 10127-10147.
|
-
[13]  | Tian, H.Z., Zhao, D., Cheng, K., Lu, L., He, M., and Hao, J. (2012), Anthropogenic Atmospheric Emissions of Antimony and Its Spatial Distribution Characteristics in China, Environmental Science $\&$ Technology, 46, 3973-3980.
|
-
[14]  | Xue, Y., Zhang, S., Zhou, Z., Wang, K., Liu, K., Wang, X., Shi, A., Xu, K., and Tian, H. (2019), Spatio-Temporal Variations of Multiple Primary Air Pollutants Emissions in Beijing of China, 2006-2015, Atmosphere, 10, 494.
|
-
[15]  | Hua, S., Tian, H., Wang, K., Zhu, C., Gao, J., Ma, Y., Xue, Y., Wang, Y., Duan, S., and Zhou, J. (2016), Atmospheric emission inventory of hazardous air pollutants from China's cement plants: Temporal trends, spatial variation characteristics and scenario projections, Atmospheric Environment, 128, 1-9.
|
-
[16]  | Gao, C., Gao, W., Song, K., Na, H., Tian, F., and Zhang, S. (2019), Spatial and temporal dynamics of air-pollutant emission inventory of steel industry in China: A bottom-up approach, Resources, Conservation and Recycling, 143, 184-200.
|
-
[17]  | Wang, K., Tian, H., Hua, S., Zhu, C., Gao, J., Xue, Y., Hao, J., Wang, Y., and Zhou, J. (2016), A comprehensive emission inventory of multiple air pollutants from iron and steel industry in China: Temporal trends and spatial variation characteristics, Beijing University of Chemical Technology (Chinese).
|
-
[18]  | Li, C. (2017), Research on the emission inventory of arsenic pollution sources in copper smelting process, Resources, Conservation and Recycling, 143, 184-200.
|
-
[19]  | Jordanova, N., Jordanova, D., Tcherkezova, E., Georgieva, B., and Ishlyamski, D. (2021), Advanced mineral magnetic and geochemical investigations of road dusts for assessment of pollution in urban areas near the largest copper smelter in SE Europe, Science of The Total Environment, 792, 148402.
|
-
[20]  | Shi, T., Xu, B., He, J., Liu, X., and Zuo, Z. (2023), Arsenic release pathway and the interaction principle among major species in vacuum sulfide reduction roasting of copper smelting flue dust, Environmental Pollution, 330, 121809.
|
-
[21]  | Wu, Z. (2021), Accounting of atmospheric heavy metal emissions and analysis of emission reduction potential in China's waste treatment industry based on life cycle assessment, Huazhong University of Science and Technology.
|
-
[22]  | Sha, Q., Lu, M., Huang, Z., Yuan, Z., Jia, G., Xiao, X., Wu, Y., Zhang, Z., Li, C., Zhong, Z., and Zheng, J. (2019), Anthropogenic atmospheric toxic metals emission inventory and its spatial characteristics in Guangdong province, China, Science of The Total Environment, 670, 1146-1158.
|
-
[23]  | Wang, L. (2021), Comparison of multiple flue gas desulfurization technologies for non-ferrous metal smelting based on data analysis, China Nonferrous Metallurgy, 50(03), 79-84.
|
-
[24]  | Li, Z., Li, S., and Guo, Y. (2019), Air emission inventory of arsenic pollution sources in China's copper smelting industry in 2017, Nonferrous Metals (Smelting Section), 10, 86-90.
|
-
[25]  | Ministry of Ecology and Environment of the People's Republic of China. (2018), Technical Guidance for the Compilation of Integrated Emission Inventories of Atmospheric Pollutants and Greenhouse Gases.
|
-
[26]  | Ministry of Ecology and Environment of the People's Republic of China. (2021), Emission Source Statistical Survey Manual for Pollution Discharge Accounting Methodologies and Coefficients.
|
-
[27]  | Ministry of Ecology and Environment of the People's Republic of China. (2018), National Industrial Pollution Source Emission Coefficient Manual for the First National Pollution Source Census.
|
-
[28]  | Chakraborty R, Sahu H. (2014), Intensification of biodiesel production from waste goat tallow using infrared radiation: Process evaluation through response surface methodology and artificial neural network, Applied Energy, 114, 827-836.
|
-
[29]  | Soulier, M., Pfaff, M., Goldmann, D., Walz, R., Geng, Y., Zhang, L., and Tercero Espinoza, L.A. (2018), The Chinese copper cycle: Tracing copper through the economy with dynamic substance flow and input-output analysis, Journal of Cleaner Production, 195, 435-447.
|
-
[30]  | Ministry of Ecology and Environment of the People's Republic of China. (2020), National Environmental Statistics Bulletin.
|
-
[31]  | Zhang, J., Sun, X., Deng, J., Li, G., Li, Z., Jiang, J., Wu, Q., and Duan, L. (2022), Emission characteristics of heavy metals from a typical copper smelting plant, Journal of Hazardous Materials, 424, 127311.
|